Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ2 O,O′]tris(thiocyanato-κN)neodymium(III)
نویسندگان
چکیده
In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thio-cyanate anions [Nd-N = 2.489 (8)-2.530 (7) Å] and six O atoms [Nd-O = 2.375 (4)-2.843 (5) Å] from three zwitterionic 2-meth-oxy-6-(4-methyl-phenyl-iminiometh-yl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing exhibits weak inter-molecular C-H⋯S hydrogen bonds, π-π inter-actions with a distance of 3.904 (7) Å between the centroids of the aromatic rings, and voids of 101 Å(3).
منابع مشابه
Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2 O,O′}tris(thiocyanato-κN)praseodymium(III) monohydrate
The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenol (HL) ligands, three independent thio-cyanate anions and an uncoordinated water mol-ecule. The Pr(III) ion is nine-coordinated. The thio-cyanate anions coordinate to the Pr(III) ion via the N atoms and the three HL ligands chelate the P...
متن کاملTris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2 O,O′}tris(thiocyanato-κN)lanthanum(III)
In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-meth-oxy-6-[(4-methyl-phen-yl)iminio-meth-yl]phenolate (L) ligands and three terminal N atoms of the thio-cyanate ions in a monocapped square-anti-prismatic environment. The L ligands chelate the La(III) ion with strong La-O(deprotonated phenolic) bo...
متن کاملTris(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III)–(nitrato-κ2 O,O′)bis(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III) (1/1)
The title co-crystal, [Eu(NCS)3(C18H15OP)3][Eu(NCS)2(NO3)(C18H15OP)3], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol-ecule contains disorder of its bidentate nitrate and two N-bound thio-cyanate anions, while the [Eu(NCS)3(OPPh3)3] complex is fully ordered. There is a weak π-π stacking inter-act...
متن کاملTris[6-methoxy-2-(phenyliminiomethyl)phenolato]-κ4 O,O′;κO 1-tris(thiocyanato-κN)samarium(III)
In the crystal structure of title compound, [Sm(NCS)(3)(C(14)H(13)NO(2))(3)], two of the zwitterionic Schiff base 6-meth-oxy-2-(phenyl-iminiometh-yl)phenolate ligands coordinate to the Sm(III) atom in a bidentate fashion via the phenolate and meth-oxy O atoms. The third Schiff base ligand is monodentate, binding only through the phenolate O atom. The coordination sphere of the eight-coordinate ...
متن کاملTris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2 O,O′}tris(thiocyanato-κN)europium(III)
The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolate (L) ligands and three independent thio-cyanate ions. In the crystal structure, the acidic H atom is located on the Schiff base N atom and hydrogen bonded to the phenolate O atom. The coordination environment of the...
متن کامل